Some days are gone since my last post but for a very good reason. I was very busy on writing down a new paper of mine. Meanwhile, frantic activity was around in the blogosphere due to EPS Conference in Grenoble. No Higgs yet but we do not despair. Being away from these distractions, I was able to analyze a main problem that was around in quantum mechanics since a nice paper by Karl-Peter Marzlin and Barry Sanders appeared in Physical Review Letters on 2004. My effort is in this paper.

But what is all about? We are aware of the concept of adiabatic variation from thermodynamics and mechanics. We know that there exist physical systems that, if we care on doing a really slow variation in time of their parameters, the state of the system does not change too much. Let me state this with an example taken from mechanics. Consider a table with a hole at the center. Through the hole there is a wire with a little ball suspended. An electric motor is keeping the wire on the table side and the ball is performing small oscillations. If the wire is kept fixed, the period of the small oscillations of this pendulum is given by the square root of the ratio between the length of the wire at the hole position and the gravity acceleration multiplied by 2 times Greek pi. Now, we can turn on the motor and vary the length of the wire with some time varying law. This will imply a variation on the frequency of the oscillations of the ball. Now, if we assume a slow variation of the length it happens a nice thing: The system displays a conserved quantity, a so called adiabatic invariant, that the energy of the system varies proportionally to the frequency. This is just an approximate conserved quantity but it is a characteristic of a slow variation of a parameter of this system. In some way, the initial state of the system, properly evolved, is maintained as time evolves as the phase space occupied by the system keeps its form. This is true provided the rate of change of the length of the wire is much smaller than the frequency of the pendulum. This is a quite general result in classical mechanics.

But, what is going on here? The explanation to this inconsistency can be traced back to a couple of papers that I and Ali Mostafazadeh wrote in the nineties (see here and here). What Born and Fock really found is the leading order of a perturbation expansion of the solution of the time dependent Schrödinger equation. This has a deep implication for the validity condition of the adiabatic approximation that represents just the leading order of this series. Indeed, let us consider a system under the effect of a perturbation. There are situations when some corrections grow without bound as time increases. These terms are unphysical as an unbounded solution violates cherished principles of physics as energy conservation, unitarity and so on. These are called secularities in literature, due to their timescales, as they were firstly discovered in the perturbation series of computations in astronomy. So, if we stop at the leading order of such a series and blindly apply the condition as devised by Born and Fock and claim for applicability, we can be just wrong. This is exactly what Marzlin, Sanders and others have shown unequivocally.

So, if you want to apply the adiabatic approximation and be sure it works, you have to do a more involved task. You have to compute the next-to-leading order correction at least and, accounting eventually for resonant behavior, identify unbounded terms. Techniques exist to resum them. After you will have this done, you will be able to identify the right condition for the adiabatic approximation to work. So, for the two-level system discussed above you will see that only when a very strong field is applied and Rabi flopping cannot happen you will get a consistent adiabatic behavior.

What is the lesson to be learned here? The simplest one is that looking in some elder literature can often help to solve a problem. Anyhow, deep into an old dusty corner of quantum mechanics is just hidden a fundamental result: Strong perturbations can be managed in quantum mechanics exactly as the weak ones. An entire new world is open from this that our founding fathers cannot be aware of.

Karl-Peter Marzlin, & Barry C. Sanders (2004). Inconsistency in the application of the adiabatic theorem Phys. Rev. Lett. 93, 160408 (2004) arXiv: quant-ph/0404022v6

Marco Frasca (2011). Consistency of the adiabatic theorem and perturbation theory arXiv arXiv: 1107.4971v1

Born, M., & Fock, V. (1928). Beweis des Adiabatensatzes Zeitschrift für Physik, 51 (3-4), 165-180 DOI: 10.1007/BF01343193

Marco Frasca (1998). Duality in Perturbation Theory and the Quantum Adiabatic Approximation Phys.Rev. A58 (1998) 3439 arXiv: hep-th/9801069v3

Ali Mostafazadeh (1996). The Quantum Adiabatic Approximation and the Geometric Phase Phys.Rev. A55 (1997) 1653-1664 arXiv: hep-th/9606053v1